Structure and Intramolecular Motions in Bicyclo[2.2.2]octane as Studied by Gas Electron Diffraction
نویسندگان
چکیده
منابع مشابه
Gas-phase structure of 2,2,2-trichloroethyl chloroformate studied by electron diffraction and quantum-chemical calculations.
The molecular structure and conformational properties of 2,2,2-trichloroethyl chloroformate, ClC(O)OCH2CCl3 were determined experimentally using gas-phase electron diffraction (GED) and theoretically based on quantum-chemical calculations at the MP2 and DFT levels of theory. Further experimental measurements such as UV-visible, IR and Raman spectroscopy were complemented with the corresponding ...
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The structure of N-fluorobis(trifluoromethylsulfonyl)imide, prepared by a relatively safe and easy method, has been determined by gas-phase electron diffraction (GED), employing the SARACEN method, with flexible restraints based on the MP2/6-311G* structure, and by X-ray crystallography at 150 K. The strongly electron-withdrawing CF(3) and SO(2)CF(3) groups make the C-S and N-S distances long, ...
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The charge transfer complex trimethylamine-borontrichloride (TMABTC1), consisting of the electron donor trimethylamine and boron-trichloride, is a stable crystalline solid. Its molecular and crystal structure has been determined by Hess [1]. The crystals are monoclinic, space group P21/m, with a = 6.492, £» = 10.216, c = 6.649 Ä, 0=116.0° and two molecules per unit cell. The bond lengths and th...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1970
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.43.2017